Graphene-Enriched Co9S8-N-C Non-Precious Metal Catalyst for Oxygen Reduction in Alkaline Media

نویسندگان

  • Gang Wu
  • Hoon T. Chung
  • Mark Nelson
  • Kateryna Artyushkova
  • Karen L. More
  • Christina M. Johnston
  • Piotr Zelenay
چکیده

In this work, a non-precious metal catalyst consisting of Co9S8 nanoparticles surrounded with nitrogen-doped graphene-like carbon (Co9S8-N-C) was developed for oxygen reduction in alkaline media. Improved activity has been measured with the Co9S8-N-C catalyst relative to Pt/C and a non-precious metal catalyst based on Fe instead of Co (Fe-N-C). An extensive physical characterization, including XRD, SEM, TEM, and XPS and electrochemical kinetic analysis was conducted to provide insight into the catalyst morphology and structure.

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تاریخ انتشار 2011